Target | Pumping | Transfer | |||
Chamber | Chamber | Tube | Total | ||
Set-Up | Flux | Flux | Flux | Flux | Comment |
Old Configuration | 52.721 | -4.114 | -0.122 | 48.485 | |
Offset | 52.844 | -3.083 | -0.630 | 49.131 | Shifted, same size coils |
Rotate Coils | -0.0519 | -0.236 | -0.078 | -0.366 | rotated coils only |
Rotate Field | 52.844 | 4.695 | -0.648 | 56.892 | ![]() |
Lengthen Transfer Tube | 52.844 | 3.076 | -0.507 | 55.413 | |
``Inflate'' Pumping Chamber | 52.844 | 9.219 | -0.648 | 61.415 | |
Long Tube, Big PC | 52.844 | 6.197 | -0.507 | 58.535 | ![]() ![]() |
The size and relative sign of the flux lead me to re-evaluate the diffusion calcualtion, as well as the calibration constant used.
![]() |
(1) |
is obtained from EPR,
and
are easily calculable - provided we understand our temperatures.
and
are above. What remains unknown is
and
. What we really care about is
. We need to separate out this factor from the equation.
Another approach would be to
![]() |
(2) |
Taking the ratio of the two
At equilibrium,
and
,
,
,
,
, and
can be calculated. However, there is no good way of knowing
, since EPR cannot be done at room temperature. (n.B., this information has been gained in the past via water calibration)
Still another approach would be to look at the signal from the upper coil:
![]() |
(3) |
And the ratio of upper to lower coil signals:
![]() |
(4) |
This situations gives us a different , as well as different fluxes. For these fluxes, the uncertainty is large and the overall value is small. So, calulating them directly does little to accurately determine
.
Now, if we assume that the temperature tests results are accurate, then we can calculate and
. From that we can calculate the ratio
(which is what has been done already, and is included in my most recent polarization numbers.) What has not been done is to extract the correct
. There is an indication that relative sign of the flux ratio helps us (this manages to offset the effect of diffusion). However, we must proceed very carefully in determining whether or not the beam was on before the NMR measurement. The ratio of the upper and lower coil measurements may help this, but it is not yet clear.
The missing pieces, as I see them, are: ,
,
and